"Munich's Legacy: The Luxury Car Brand Redefining Excellence with the 'S-Class' and 'E-Class' Models"

 The luxury car brand associated with the "S-Class" and "E-Class" models is not founded in Munich. The correct answer is Mercedes-Benz, which is a German automobile manufacturer headquartered in Stuttgart, Germany. The "S-Class" and "E-Class" are well-known model lines produced by Mercedes-Benz, renowned for their luxury and performance features.